Can you do courier work in the family car?

Im working full time to keep the family together and the mortgage paid and my husband who was made redundent a few months ago has seen on the internet that you can use a family car to do courier work in delivering laptops and valuable thing is this true? I need him out working but we can’t afford to throw time and money away on things that will never work. He’s a good man and decent and honest and knows his way round the country. I just need to know if its pie in the sky. Thanks Tess.
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